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1 article(s) from Förtsch, Sebastian

Selenophene-containing heterotriacenes by a C–Se coupling/cyclization reaction

Pierre-Olivier Schwartz,
Sebastian Förtsch,
Astrid Vogt,
Elena Mena-Osteritz and
Peter Bäuerle

Beilstein J. Org. Chem. 2019, 15, 1379–1393, doi:10.3762/bjoc.15.138

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Figure 1: Heterotriacenes DTT 1, DTS 2, DST 3, and DSS 4 with varying number of selenium atoms and fused sele...

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Scheme 1: Synthesis of heterotriacenes DTT 1 and DTS 2 via copper-catalyzed cross-coupling reactions.

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Scheme 2: Synthesis of selenolotriacenes DST 3 and DSS 4.

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Figure 2: Single crystal X-ray structure analysis of selenolotriacene DST 3, (a) individual molecule and atom...

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Figure 3: Single crystal X-ray structure analysis of selenolotriacene DST 3: (a) partial overlap of stacked a...

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Figure 4: DFT quantum chemical calculated geometry of DTT 1 and general atom labelling for all heterotriacene...

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Figure 5: Representative electron density of frontier orbitals LUMO, HOMO, and HOMO-1 for heterotriacene DSS 4...

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Figure 6: Normalized absorption spectra of heteroacenes DTT 1 (black line), DTS 2 (blue line), DST 3 (green l...

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Figure 7: Energy diagram of the frontier molecular orbitals of heterotriacenes 1–4.

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Figure 8: Multisweep voltammograms for the electrochemical polymerization of monomeric heterotriacene DST 2 i...

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Scheme 3: Oxidative polymerization of heterotriacenes 1–4 to corresponding conjugated polymers P1–P4.

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Published 24 Jun 2019

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